Electronic structure and reactivity of Li1-xMn2O4 cathode

被引：24

作者：

Molenda, J ^{[1
]}

Swierczek, K ^{[1
]}

Molenda, M ^{[1
]}

Marzec, J ^{[1
]}

机构：

[1] Stanislaw Staszic Univ Min & Met, Dept Solid State Chem, PL-30059 Krakow, Poland

来源：

SOLID STATE IONICS | 2000年 / 135卷 / 1-4期

关键词：

Li1-xMn2O4; lithium intercalation; transport properties;

D O I：

10.1016/S0167-2738(00)00331-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The investigations of low temperature electrical and structural properties of the Li1-xMn2O4 cathode as a function of lithium concentration are presented. Structure studies of deintercalated spinel revealed the existence of a broad (300-200 K) phase transition from cubic into orthorhombic phase also confirmed by DSC results. Thermoelectric power and electrical conductivity measurements indicate that the manganese spinel undergoes a modification of electronic structure during intercalation process. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：53 / 59

页数：7

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