New carbenegold(I) complexes synthesized by the "acac method"

被引：30

作者：

Vicente, J

Chicote, MT

Abrisqueta, MD

Alvarez-Falcón, MM

de Arellano, MCR

Jones, PG

机构：

[1] Univ Murcia, Fac Quim, Dept Quim Inorgan, Grp Quim Organomet, E-30071 Murcia, Spain

[2] Univ Valencia, Fac Farm, Dept Quim Organ, Valencia 46100, Spain

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 21期

关键词：

D O I：

10.1021/om030372r

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [AuCl{C(NEt2)(NHBu)-Bu-t}] with Tl(acac)] (1:1) gives [Au(C-acac){C(NEt2)-(NHBu)-Bu-t}] (1). Complex 1 reacts with 2-pyridinethiol (HSpy-2), C6H4(Cequivalent toCH)(2)-1,3 (2:1), [Ph3PCH2CO2Me]ClO4, [Me3S(O)]ClO4, or [Me3NH]ClO4 to give, respectively, [Au(Spy-2)-{C(NEt2)(NHBu)-Bu-t}] (2), [{AuC(NEt2)(NHBu)-Bu-t}(2)(mu-Cequivalent toCC(6)H(4)Cequivalent toC-3)] (3), [Au{C(NEt2)(NHBu)-Bu-t}-{CH(PPh3)CO2Me}]ClO4 (4), [Au{C(NEt2)(NHBu)-Bu-t}{CH2S(O)Me-2}]ClO4 (5), or [Au{C(NEt2)(NHBu)-Bu-t}(NMe3)]ClO4 (6). The crystal structures of 1, 3, and 5 have been determined.

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页码：4327 / 4333

页数：7

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