Cu(acac)2 immobilized in ionic liquids:: A novel and recyclable catalytic system for aziridination of olefins using PhI=NTs as nitrene donor

被引：29

作者：

Kantam, ML ^{[1
]}

Neeraja, V ^{[1
]}

Kavita, B ^{[1
]}

Haritha, Y ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Hyderabad 500007, Andhra Pradesh, India

来源：

SYNLETT | 2004年 / 03期

关键词：

copper acetylacetonate; ionic liquids; aziridination; olefins; PhI=NTs;

D O I：

10.1055/s-2004-815420

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Copper(II) acetylacetonate immobilized in ionic liquids efficiently catalyzes aziridination of olefins in good yields at a faster rate than the earlier reported methods using PhI=NTs as a nitrene donor with easy catalyst/solvent recycling.

引用

页码：525 / 527

页数：3

共 47 条

[1] Asymmetric synthesis of N-aryl aziridines
Aires-de-Sousa, J
Prabhakar, S
Lobo, AM
Rosa, AM
Gomes, MJS
Corvo, MC
Williams, DJ
White, AJP
[J]. TETRAHEDRON-ASYMMETRY, 2002, 12 (24) : 3349 - 3365
[2] Nitrogen atom transfer to alkenes utilizing chloramine-T as a nitrogen source
Ando, T
Minakata, S
Ryu, I
Komatsu, M
[J]. TETRAHEDRON LETTERS, 1998, 39 (3-4) : 309 - 312
[3] Palladium(II)-promoted aziridination of olefins with bromamine T as the nitrogen transfer reagent
Antunes, AMM
Marto, SJL
Branco, PS
Prabhakar, S
Lobo, AM
[J]. CHEMICAL COMMUNICATIONS, 2001, (05) : 405 - 406
[4] 3-Acetoxyaminoquinazolinones (QNHOAc) as aziridinating agents: ring-opening of N-(Q)-substituted aziridines
Atkinson, RS
[J]. TETRAHEDRON, 1999, 55 (06) : 1519 - 1558
[5] Lewis acid-catalyzed synthesis of aziridines
Casarrubios, L
Perez, JA
Brookhart, M
Templeton, JL
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (24) : 8358 - 8359
[6] Investigations in the transition metal catalyzed aziridination of olefins, amination, and other insertion reactions with Bromamine-T as the source of nitrene
Chanda, BM
Vyas, R
Bedekar, AV
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (01) : 30 - 34
[7] Chauvin Y, 1995, ANGEW CHEM INT EDIT, V34, P2698
[8] Asymmetric Mannich-type reactions catalyzed by indium(III) complexes in ionic liquids
Chen, SL
Ji, SJ
Loh, TP
[J]. TETRAHEDRON LETTERS, 2003, 44 (11) : 2405 - 2408
[9] CHENNA PHD, 2003, TETRAHEDRON, V59, P1009
[10] Díaz-Requejo MM, 2001, J ORGANOMET CHEM, V617, P110

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