Synthesis of clay nanocomposite materials by light-induced crosslinking polymerization

被引:82
作者
Benfarhi, S
Decker, C
Keller, L
Zahouily, K
机构
[1] Univ Haute Alsace, Ecole Natl Super Chim, CNRS, Dept Photochim Gen,UMR 7525, F-68200 Mulhouse, France
[2] Photo N Polymers Experts, F-68200 Mulhouse, France
关键词
UV-curing; nanocomposites; acrylates; epoxides; organoclay;
D O I
10.1016/j.eurpolymj.2003.11.009
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Different types of nanocomposite materials have been synthetized within seconds at ambient temperature, by photoinitiated crosslinking polymerization, of epoxy, vinyl ether and acrylate-based resins containing a small amount (3 wt%) of an organoclay filler. The curing process was followed quantitatively by infrared spectroscopy through the decrease upon UV exposure of the IR bands characteristic of the functional groups. The silicate nanoparticles were found to have no effect on the polymerization kinetics. The UV-cured nanocomposites proved to be more flexible and impact resistant than the corresponding microcomposites. This method of synthesis of nanocomposites presents the advantages associated with the UV-curing technology, namely a solvent-free resin transformed rapidly at ambient temperature into a chemically resistant material, with a minimum consumption of energy. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码:493 / 501
页数:9
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