Catalytic conversion of butadiene to ethylbenzene over the nanoporous nickel(II) phosphate, VSB-1

被引:57
作者
Chang, JS
Park, SE
Gao, QM
Férey, G
Cheetham, AK
机构
[1] Korea Res Inst Chem Technol, Catalysis Ctr Mol Engn, Taejon 305606, South Korea
[2] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA
[3] Univ Versailles St Quentin, CNRS, Inst Lavoisier, UMR 173, F-78035 Versailles, France
关键词
D O I
10.1039/b009160j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The large-pore nickel(ii) phosphate, VSB-1, shows excellent selectivity (> 80%) for the dehydrocyclodimerization of butadiene to ethylbenzene at 400 degreesC; conversion to 4-vinylcyclohexene and oligomeric byproducts is <5% in each case.
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页码:859 / 860
页数:2
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