Reactions of aroylthioureas with acetylenic esters and dibenzoyl ethylene. Selectivity towards the formation of new 1,3-thiazines

被引:26
作者
Aly, Ashraf A. [1 ]
Ahmed, Essam K. [1 ]
El-Mokadam, Khalad M. [1 ]
机构
[1] Menia Univ, Fac Sch, Dept Chem, El Mina, Egypt
关键词
D O I
10.1002/jhet.5570440630
中图分类号
O62 [有机化学];
学科分类号
070303 [有机化学]; 081704 [应用化学];
摘要
A series of 1,3-thiazines has been synthesized by the reactions of N-aroylsubstituted thioureas with ethyl propiolate, dimethyl but-2-ynedioate and (E)-1,4-diphenyl-but-2-ene-1,4-dione. The reaction of antipyrinylphenyl thiourea with at-deficient acetylenic reagents did not afford the corresponding 1,3-thiazines, whereas pyrrolo-pyrazolopyrimidines were obtained.
引用
收藏
页码:1431 / 1438
页数:8
相关论文
共 21 条
[1]
AGAWAL SK, 1987, INDIAN J CHEM, V26, P642
[2]
ALLINGER NL, 1988, PM3 FORCE FIELD PROG
[3]
Aly A.A., 2006, J SULFUR CHEM, V27, P419, DOI [10.1080/17415990600862960, DOI 10.1080/17415990600862960]
[4]
Cycloadditions of α-(4-[2.2]paracyclophanyl)-N-methyl nitrone [J].
Aly, AA ;
Hopf, H ;
Jones, PG ;
Dix, I .
TETRAHEDRON, 2006, 62 (18) :4498-4505
[5]
Cycloadditions to alkenyl[2.2]paracyclophanes [J].
Aly, AA ;
Ehrhardt, S ;
Hopf, H ;
Dix, I ;
Jones, PG .
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2006, 2006 (02) :335-350
[7]
ALY AA, 2007, J SULF CHEM, V28, P737
[8]
ALY AA, 2007, J SULF CHEM, V28, P285
[9]
New cycloadditions of (E)-N,α-dimethyl-α-(4-[2.2]paracylophanyl)nitrone [J].
Aly, Ashraf A. ;
Hopf, Henning ;
Ernst, Ludger ;
Dix, Ina ;
Jones, Peter G. .
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2006, 2006 (13) :3001-3006
[10]
Reactions of 5-mercaptoazoles and pyridine-2-thiones with acetylenic esters. Selectivity of the formation of novel fused thiazin-4-ones and thiazolidin-4-ones [J].
Bakulev, VA ;
Berseneva, VS ;
Belskaia, NP ;
Morzherin, YY ;
Zaitsev, A ;
Dehaen, W ;
Luyten, I ;
Toppet, S .
ORGANIC & BIOMOLECULAR CHEMISTRY, 2003, 1 (01) :134-139