Preparation and characterization of inorganic fluorides - Fullerenes compounds

被引：7

作者：

Hamwi, A ^{[1
]}

Latouche, C

Burteaux, B

Dupuis, J

机构：

[1] Univ Blaise Pascal, Chim Solides Lab, F-63177 Aubiere, FRANCE

[2] Univ Blaise Pascal, Lab Sci & Mat Elect & Automat, F-63177 Aubiere, FRANCE

来源：

FULLERENE SCIENCE AND TECHNOLOGY | 1996年 / 4卷 / 06期

关键词：

D O I：

10.1080/10641229608001175

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Reaction of metallic fluorides : WF6, TaF5, NbF5 and TiF4 with C-60/C-70 extract was pet-formed at appropriate temperatures. MoF5 and BF3 fluorides do not react. Chemical formulas based on mass uptake show MFn/C-60 ratios up to 2.00. Compounds were analysed by means of X-ray diffraction, FT-IR and NMR spectroscopies. The presence of neutral fluorides and associated anionic species is put forward and it is shown that MFn compounds do not act as fluorination agents. Electrical conductivity measurements are also presented.

引用

页码：1213 / 1226

页数：14

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