Fe/Sr ratio effect on magnetic properties of strontium ferrite powders synthesized microwave-induced combustion process

被引:97
作者
Fu, YP [1 ]
Lin, CH [1 ]
机构
[1] Wu Feng Inst Technol, Dept Chem Engn, Chiayi, Taiwan
关键词
strontium ferrite powder; combustion synthesis; VSM; saturation magnetization; intrinsic coercive force;
D O I
10.1016/j.jallcom.2004.04.148
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 [物理化学]; 081704 [应用化学];
摘要
Strontium hexaferrite nano-particles were successfully synthesized by microwave-induced combustion process. Magnetic properties of strontium ferrite powders with Fe/Sr ratios varying from 11 to 12 and different annealing temperatures range of 850 to 1050degreesC were studied. The resultant powders were investigated by XRD, TEM, SEM, VSM, TG/DTA, and surface area measurement. The optimum magnetic properties of strontium ferrite powders were as follows: the composition with an Fe/Sr ratio of 11.6 annealed at 1000degreesC for 2 It possessed a saturation magnetization of 62 emu/g and an intrinsic coercive force of 1950 Oe. Moreover, the microwave-heated strontium ferrite powders with a Fe/Sr ratio of 11.6 annealed at various temperatures had particle size ranging from 52 to 78 nm. Low-coercivity strontium ferrite powders can be obtained by microwave-induced combustion process without doping with metal elements such as Co-Ti, Co-Sn, Zn-Sn, etc. These low coercive strontium ferrite powders are suitable for magnetic recording applications in hard disks, floppy disks, video tapes, etc. (C) 2004 Elsevier BN. All rights reserved.
引用
收藏
页码:222 / 227
页数:6
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