Kinetics of O-2+TEOS gas-phase chemical reactions in a remote RF plasma reactor with electron spin resonance

被引:10
作者
Janca, J
Talsky, A
Zvonicek, V
机构
[1] Department of Physical Electronics, Faculty of Science, Masaryk University, Brno, 611 37
关键词
TEOS; ESR; rate coefficients; remote microwave discharge;
D O I
10.1007/BF01570177
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Kinetics of the reaction O + TEOS (tetraethoxysilane) was studied by means of the ESR method Molecular oxygen was partially atomized by a 13.56-MHz discharge in the quartz tube that passed inside an ESR cavity. TEOS vapors were injected between the discharge and ESR cavity. O-atom loss occurring due to the reaction of atomic oxygen with TEOS molecules was measured and the rate coefficient k(1) of the reaction of O atoms with TEOS molecules was determined The obtained results could be used for deposition process simulations.
引用
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页码:187 / 194
页数:8
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