Deactivation studies of Rh/Ce0.8Zr0.2O2 catalysts in low temperature ethanol steam reforming

被引：38

作者：

Platon, Alex ^{[1
]}

Roh, Hyun-Seog ^{[1
]}

King, David L. ^{[1
]}

Wang, Yong ^{[1
]}

机构：

[1] Pacific NW Natl Lab, Richland, WA 99352 USA

来源：

TOPICS IN CATALYSIS | 2007年 / 46卷 / 3-4期

关键词：

ethanol; steam reforming; catalyst deactivation;

D O I：

10.1007/s11244-007-9007-6

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Rapid deactivation of Rh/Ce0.8Zr0.2O2 catalysts during low temperature ethanol steam reforming was studied. A significant build-up of reaction intermediates, instead of carbon deposit, was observed at low reaction temperatures. This appears to be the cause of rapid catalyst deactivation. Co-feed experiments indicated that possible intermediate products acetone and ethylene caused more severe catalyst deactivation than other oxygenates such as acetic acid and acetaldehyde.

引用

收藏

页码：374 / 379

页数：6

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