A turbidimetric method for the rapid evaluation of MWF emulsion stability

被引:14
作者
Deluhery, J [1 ]
Rajagopalan, N [1 ]
机构
[1] Illinois Waste Management & Res Ctr, Champaign, IL 61820 USA
关键词
metalworking fluid; oil-in-water emulsions; stability; turbidity;
D O I
10.1016/j.colsurfa.2004.12.001
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 [物理化学]; 081704 [应用化学];
摘要
The stability of metalworking emulsions is a critical characteristic impacting its usefulness as a lubricant and rust inhibitor. Loss of stability usually results in replacement of the fluid leading to both economic loss and environmental discharge. In this paper, the loss of stability caused by accumulation of hardness ions is examined by a turbidimetdc method. The method is based on following the change in the wavelength exponent of the emulsions caused by changing particle size. The stability as determined by this method is compared to conventional testing based on phase separation over 24 h. The turbidimetric method is shown to be a more conservative estimate of emulsion stability. The simplicity of the method makes it useful for both product formulation and process control. (c) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:145 / 149
页数:5
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