Hydrothermal synthesis and structure of a three-dimensional open-framework cobalt molybdenum(VI) phosphate containing ethylenediammonium ions:: (C2H9N2)6[Co3Mo4P4O28]

被引:32
作者
Lu, JJ [1 ]
Xu, Y [1 ]
Goh, NK [1 ]
Chia, LS [1 ]
机构
[1] Nanyang Technol Univ, Sch Sci, Div Chem, Singapore 259756, Singapore
关键词
D O I
10.1039/a804693j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first microporous cobalt molybdenum(VI) phosphate, crystallised under hydrothermal conditions, is constructed from unique CoMo2P tetrahedral units connected by CoO4 tetrahedra and by sharing corners; the framework contains interlocking cavity units and unusual 7-ring intersecting channels that are filled with charge-compensating ethylenediammonium ions.
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页码:1709 / 1710
页数:2
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