Solvent effects on the piezochromism of molybdenum(IV) and tungsten(IV) anions [M(CN)3O(diimine)]-

被引：8

作者：

Nowicka, B

Burgess, J

Parsons, SA

Samotus, A

Szklarzewicz, J

机构：

[1] Jagiellonian Univ, Fac Chem, PL-30060 Krakow, Poland

[2] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England

来源：

TRANSITION METAL CHEMISTRY | 1998年 / 23卷 / 03期

关键词：

D O I：

10.1023/A:1015729421060

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Solvatochromism of the [Mo(CN)(3)O(phen)](-) ion has been studied. Solvent effects on pressure dependence (up to 1.25 kbar) of wavelengths of maximum absorption for charge-transfer bands of several molybdenum(IV) and tungsten(IV) complexes, [M(CN)(3)O(diimine)](-)(M = Mo or W), are described. The effects of applied pressure are larger for less polar unstructured solvents than for highly polar hydrogen-bonded solvents.

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页码：317 / 319

页数：3

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