Carbon nanofilm with a new structure and property

被引:100
作者
Horiuchi, S
Gotou, T
Fuijwara, M
Sotoaka, R
Hirata, M
Kimoto, K
Asaka, T
Yokosawa, T
Matsui, Y
Watanabe, K
Sekita, M
机构
[1] Mitsubishi Gas Chem Co Inc, Corp Res Lab, Tsukuba, Ibaraki 3004247, Japan
[2] Natl Inst Mat Sci, Adv Mat Lab, Tsukuba, Ibaraki 3050044, Japan
来源
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS | 2003年 / 42卷 / 9AB期
关键词
carbon nanofilm; HRTEM; ED; structure analysis; thickness; stacking sequence; EELS; O/C; semiconductor;
D O I
10.1143/JJAP.42.L1073
中图分类号
O59 [应用物理学];
学科分类号
摘要
We have prepared a carbon film of nanometer thickness, which is called here a carbon nanofilm (CNF), starting from the oxidation of graphite. The structure and thickness of the CNF are determined by high-resolution transmission electron microscopy and electron diffraction. The structure is of a new type (S.G.: P3), in which carbon six-membered-ring planes are stacked with the sequence of... AA.... According to electron energy loss spectroscopy, a substantial amount of oxygen is detected but the molar ratio of oxygen to carbon is possibly decreased to less than 0.1. The CNF changes from an insulator to a semiconductor when reduced on heating at 250degreesC.
引用
收藏
页码:L1073 / L1076
页数:4
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