Triaquatris(μ-oxydiacetato)europium(III)lanthanum(III) pentahydrate

被引：13

作者：

Baggio, R ^{[1
]}

Garland, MT

Perec, M

机构：

[1] Comis Nacl Energia Atom, Dept Fis, RA-1429 Buenos Aires, DF, Argentina

[2] Univ Chile, Fac Ciencias Fis & Matemat, Dept Fis, Santiago, Chile

[3] UNBA, Fac Ciencias Exactas & Nat, Dept Quim Inorgan Analit & Quim Fis, Buenos Aires, DF, Argentina

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷

关键词：

D O I：

10.1107/S0108270197017356

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new heterobimetallic complex [{LaEu(oda)(3)(H2O)(3).-5H(2)O}n] (oda = -O2CCH2OCH2CO2-) has been synthesized and structurally characterized. Three tridentate oda ligands are coordinated to the smaller Eu-III cation, while six adjacent outer carboxylate O atoms and three metal-bound water O atoms are bonded to the larger La-III cation. The structure consists of a three-dimensional network with the metal centers bridged by oda carboxylate groups, with Eu...La separations of 6.95 (1) Angstrom.

引用

页码：591 / 594

页数：4

共 17 条

[1] LASER SPECTROSCOPIC AND X-RAY STRUCTURAL INVESTIGATION OF EUROPIUM(III)-OXYDIACETATE COMPLEXES IN SOLUTION AND IN THE SOLID-STATE [J].

ALBIN, M ;

WHITTLE, RR ;

HORROCKS, WD .

INORGANIC CHEMISTRY, 1985, 24 (26) :4591-4594

[2] SYSTEMATIC ANALYSIS OF STRUCTURAL DATA AS A RESEARCH TECHNIQUE IN ORGANIC-CHEMISTRY [J].

ALLEN, FH ;

KENNARD, O ;

TAYLOR, R .

ACCOUNTS OF CHEMICAL RESEARCH, 1983, 16 (05) :146-153

[3] Synthesis and X-ray structure of the novel polymeric lanthanum(III) 2,2'-oxydiacetate [La-2(C4H4O5)(3)(H2O)(3)center dot 5H(2)O](n) [J].

Baggio, R ;

Garland, MT ;

Perec, M ;

Vega, D .

INORGANIC CHEMISTRY, 1996, 35 (08) :2396-&

[4]

BAGGIO R, 1998, IN PRESS INORG CHIM

[5]

Cotton F.A., 1988, Advanced Inorganic Chemistry

[6] RELATIONSHIPS BETWEEN THE CARBON-OXYGEN STRETCHING FREQUENCIES OF CARBOXYLATO COMPLEXES AND THE TYPE OF CARBOXYLATE COORDINATION [J].

DEACON, GB ;

PHILLIPS, RJ .

COORDINATION CHEMISTRY REVIEWS, 1980, 33 (03) :227-250

[7] STRUCTURAL STUDIES ON RARE-EARTH CARBOXYLATES .27. CRYSTAL-STRUCTURE OF ERBIUM TRIS(OXYDIACETATO)ERBATE HEXAHYDRATE, CONTAINING 8-COORDINATED AND 9-COORDINATED ERBIUM IONS [J].

ELDING, I .

ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1977, 31 (01) :75-77

[8] ON ENANTIOMORPH-POLARITY ESTIMATION [J].

FLACK, HD .

ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV) :876-881

[9] ABSOLUTE-CONFIGURATION AND CIRCULAR-DICHROISM OF THE LANTHANIDE COMPLEX TRISODIUM TRIS(OXYDIACETATO)EUROPATE(III) BIS(SODIUM TETRAFLUOROBORATE) HEXAHYDRATE [J].

FRONCZEK, FR ;

BANERJEE, AK ;

WATKINS, SF ;

SCHWARTZ, RW .

INORGANIC CHEMISTRY, 1981, 20 (08) :2745-2746

[10]

Nakamoto K., 2009, Infrared and Raman Spectra of Inorganic and Coordination Compounds: Part A: Theory and Applications in Inorganic Chemistry, V6th ed.

← 1 2 →