Kinetics of catalytic carbon black oxidation

被引:51
作者
Bokova, MN [1 ]
Decarne, C
Abi-Aad, E
Pryakhin, AN
Lunin, VV
Aboukaïs, A
机构
[1] Univ Littoral, MREI, Lab Catalyse & Environm, EA 2598, Dunkerque, France
[2] Moscow MV Lomonosov State Univ, Dept Chem, Catalysis & Gas Electrochem Lab, Moscow, Russia
关键词
catalytic soot oxidation; Ce-Al oxides; oxidation kinetics; activation energy; pre-exponential factor; thermal analysis;
D O I
10.1016/j.tca.2004.11.011
中图分类号
O414.1 [热力学];
学科分类号
摘要
Kinetics of the catalyzed oxidation of carbon black (CB) in the presence of Ce-Al oxides is studied. The activation energies for CB combustion are determined from the DTA-TG data. The catalysts performances are compared on the basis of thermal analysis and calculated kinetic parameters. In this investigation, a convenient method for the rapid calculation of the kinetic parameters from single DTA-TG curves is proposed. (c) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:165 / 171
页数:7
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