Observation of polymer interface instability

被引：2

作者：

Orihara, H ^{[1
]}

Shibuya, T

Ujiie, S

机构：

[1] Nagoya Univ, Ctr Integrated Res Sci & Engn, Nagoya, Aichi 4648603, Japan

[2] Nagoya Univ, Grad Sch Engn, Dept Appl Phys, Nagoya, Aichi 4648603, Japan

[3] Shimane Univ, Fac Sci & Engn, Dept Mat Sci, Matsue, Shimane 6908504, Japan

来源：

POLYMER | 2003年 / 44卷 / 26期

基金：

日本学术振兴会;

关键词：

interface; instability; polymer blend;

D O I：

10.1016/j.polymer.2003.10.039

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We observed with a confocal scanning laser microscope the interface between a liquid crystalline polymer (LCP) and polydimethylsiloxane (DMS) after they made contact. The initially flat interface became corrugated and the characteristic length of the corrugation increased gradually. The coarsening rate was found to be controlled by the viscosity (the molecular weight) of the DMS; as the viscosity was increased the rate became slower. The present interfacial instability may be related to the diffusion of the low molecular weight DMS into the LCP. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：8133 / 8137

页数：5

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