Transformation of 1,5-and 1,6-dienes to carbocycles by hydrozirconation and oxidation with cerium(IV) compounds

被引：9

作者：

Azemi, T ^{[1
]}

Kitamura, M ^{[1
]}

Narasaka, K ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

TETRAHEDRON | 2004年 / 60卷 / 06期

关键词：

1,5; and 1,6-dienes; radical cyclization; alkyl zirconocene; cerium(IV);

D O I：

10.1016/j.tet.2003.08.075

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cyclopentane and cyclohexane derivatives are prepared from 1,5- and 1,6-dienes in a one pot procedure by hydrozirconation, then oxidation of the generated 5- and 6-alkenylzirconocene chlorides with ammonium hexanitratocerate. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：1339 / 1344

页数：6

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