Electrochemical characterization of plasticized polyelectrolyte based on lithium-N(4-sulfophenyl) maleimide

被引：9

作者：

Xu, W ^{[1
]}

Siow, KS ^{[1
]}

Gao, ZQ ^{[1
]}

Lee, SY ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore 119260, Singapore

来源：

ELECTROCHIMICA ACTA | 1999年 / 44卷 / 13期

关键词：

plasticized polyelectrolyte; ionic conductivity; lithium interface; impedance spectroscopy;

D O I：

10.1016/S0013-4686(98)00348-X

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Thermal behavior and electrochemical properties of propylene carbonate (PC) plasticized polyelectrolyte based on poly[lithium-N(4-sulfophenyl) maleimide-co-methoxy oligo(oxyethylene) methacrylate] have been investigated. This PC plasticized polyelectrolyte with a PC content of 54.5 wt% has an ionic conductivity of 1.8 x 10(-5) S cm(-1) at ambient temperature and a wide electrochemical window. Passivation phenomena occurring at the interface between the PC plasticized polyelectrolyte and a Li electrode were particularly evaluated and discussed. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：2287 / 2296

页数：10

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