Near-net-shape forming of metallic bipolar plates for planar solid oxide fuel cells by induction plasma spraying

被引:24
作者
Henne, R
Müller, M
Pross, E
Schiller, G
Gitzhofer, F
Boulos, M
机构
[1] Deutsch Zentrum Luft & Raumfahrt, Inst Tech Thermodynam, D-70569 Stuttgart, Germany
[2] Univ Sherbrooke, Dept Genie Chim, Sherbrooke, PQ J1K 2R1, Canada
[3] HC Starck GMBH & Co KG, D-79725 Laufenburg, Germany
关键词
induction plasma deposition; metallic bipolar plate; near-net-shape forming; solid oxide fuel cell; spray angle; vacuum plasma spraying;
D O I
10.1361/105996399770350638
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In one of the present designs of solid oxide fuel cells (SOFC), metallic bipolar plates with gas channels on the surface are used, which consist of a chromium alloy and are manufactured by a time consuming and costly multistep process. To reduce the production time and costs, attempts were made to develop an alternative near-net-shape production method based on RF-induction plasma spray technology, With this process raw powders, as applied fur the "conventional" sintering route as well as recycled powders from used bipolar plates, have been applied, The process parameters were adapted to both powders, and the obtained products mere qualified. The near-net-shape production requires the formation of a gas channel structure already with the spray process using structured substrate, Therefore, different spray angles occur during the deposition process, The influence of the spray angle on the microstructure of the free-standing parts was investigated, The required gas tightness for grooved profiles with relatively large channel depths and widths can only be achieved using spray angles between 90 degrees and approximately 60 degrees. Then a tilting of the substrate and an adapted design of the gas channel profiles are needed to fulfill the structural requirements for the bipolar plates.
引用
收藏
页码:110 / 116
页数:7
相关论文
共 17 条
[1]  
BORDEAUX F, 1991, THERMAL SHOCK RESIST, P127
[2]  
Boulos M.I., 1992, J THERM SPRAY TECHN, V1, P33
[3]   THE INDUCTIVELY COUPLED RF (RADIO-FREQUENCY) PLASMA [J].
BOULOS, MI .
PURE AND APPLIED CHEMISTRY, 1985, 57 (09) :1321-1352
[4]   The inductively coupled radio frequency plasma [J].
Boulos, MI .
HIGH TEMPERATURE MATERIAL PROCESSES, 1997, 1 (01) :17-39
[5]  
BRUCKNER B, 1996, P 1996 FUEL CELL SEM, P155
[6]  
DRENCKHAHN W, 1991, BRENNST-WARME-KRAFT, V43, P424
[7]  
GUNTHER C, 1996, P 2 EUR SOL OX FUEL, V2, P491
[8]  
HENNE R, 1997, Patent No. 10299542307
[9]   Chromium vapor species over solid oxide fuel cell interconnect materials and their potential for degradation processes [J].
Hilpert, K ;
Das, D ;
Miller, M ;
Peck, DH ;
Weiss, R .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (11) :3642-3647
[10]  
JANOUSEK M, 1997, VDI FORTSCHRITTBERIC, V5