Iron-catalyzed asymmetric sulfide oxidation with aqueous hydrogen peroxide

被引：227

作者：

Legros, J ^{[1
]}

Bolm, C ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, D-52056 Aachen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 44期

关键词：

asymmetric catalysis; iron; oxidation; peroxides; sulfoxides;

D O I：

10.1002/anie.200352635

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An iron in the fire: Iron-based catalysts promote the asymmetric oxidation of alkyl aryl sulfides to the corresponding sulfoxides with up to 90% ee (see scheme). Simple hydrogen peroxide (30% in water) serves as the terminal oxidant.

引用

页码：5487 / 5489

页数：3

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