Implications of remote water molecules on the electron transfer coupled processes at a nonporphyrinic Mn(III)-hydroxido complex

被引：17

作者：

El Ghachtouli, Sanae ^{[1
,2
]}

Lassalle-Kaiser, Benedikt ^{[2
,3
]}

Dorlet, Pierre ^{[4
]}

Guillot, Regis ^{[2
]}

Anxolabehere-Mallart, Elodie ^{[1
]}

Costentin, Cyrille ^{[1
]}

Aukauloo, Ally ^{[2
,5
]}

机构：

[1] Univ Paris Diderot, Electrochim Mol Lab, UMR CNRS P7 7591, F-75205 Paris 13, France

[2] Univ Paris 11, ICMMO, UMR 8182, F-91405 Orsay, France

[3] Univ Calif Berkeley, Lawrence Berkeley Lab, Phys Biosci Div, Berkeley, CA 94720 USA

[4] CNRS, URA 2096, Lab Stress Oxydant & Detoxicat, F-91191 Gif Sur Yvette, France

[5] CEA, IBiTec S, SM SB2, F-91191 Gif Sur Yvette, France

来源：

ENERGY & ENVIRONMENTAL SCIENCE | 2011年 / 4卷 / 06期

关键词：

PHOTOSYSTEM-II; MONONUCLEAR; ACTIVATION; OXIDATION; DESIGN; MANGANESE(III); CHEMISTRY; DINUCLEAR; DIOXYGEN; OXYGEN;

D O I：

10.1039/c1ee01078f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrochemical studies of a new Mn(III)(OH) complex clearly evidence that the presence of outer spheres water molecules is essential for the reversibility of Mn-III/II and Mn-IV/III redox processes. In the Mn-III/II case we found an isotope effect for D2O and (OH2)-O-18 allowing us to propose a mechanism for H2O/HO- ligand exchange coupled electron transfer activation of Mn-OH2

引用

页码：2041 / 2044

页数：4

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