Chromogenic Detection of Nerve Agent Mimics by Mass Transport Control at the Surface of Bifunctionalized Silica Nanoparticles

被引：63

作者：

Climent, Estela ^{[1
]}

Marti, Almudena ^{[2
,3
]}

Royo, Santiago ^{[1
]}

Martinez-Manez, Ramon ^{[1
]}

Dolores Marcos, M. ^{[1
]}

Sancenon, Felix ^{[1
]}

Soto, Juan ^{[1
]}

Costero, Ana M. ^{[2
,3
]}

Gil, Salvador ^{[2
,3
]}

Parra, Margarita ^{[2
,3
]}

机构：

[1] Univ Politecn Valencia, Dept Quim, Univ Valencia, Ctr Mixto,Inst Reconocimiento Mol & Desarrollo Te, Valencia 46022, Spain

[2] Univ Valencia, Univ Politecn Valencia, Ctr Mixto, Inst Reconocimiento Mol & Desarrollo Tecnol, E-46100 Valencia, Spain

[3] Univ Valencia, Fac Ciencias Quim, Dept Quim Organ, E-46100 Valencia, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 34期

关键词：

chromogenic probes; dyes/pigments; nanoparticles; nerve agents; sensors; CHEMICAL WARFARE AGENTS; SENSORS; SIMULANTS; BINDING; REPORTER; OXIMATE; GROWTH; GASES;

D O I：

10.1002/anie.201001088

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

"Figure Presented" Limited access: Silica nanoparticles functionalized with alcohols and thiols have been used for the chromofluorogenic detection of nerve agent mimics. In the absence of the mimics, the thiol groups (yellow circles) react with squaraine dyes (blue diamonds) and result in the bleaching of the solution. In the presence of the mimics, the squaraine-thiol reaction is inhibited (see picture; red triangle= hydroxy, empty triangles = silicate, blue circle = nitrogen). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.angewandte.org.

引用

页码：5945 / 5948

页数：4

共 39 条

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