A tridentate ligand for preparation of bisterpyridine-like ruthenium(II) complexes with an increased excited state lifetime

被引：38

作者：

Wolpher, H

Johansson, O

Abrahamsson, M

Kritikos, M

Sun, LC

Åkermark, B

机构：

[1] Univ Stockholm, Arrhenius Lab, Dept Organ Chem, S-10691 Stockholm, Sweden

[2] Uppsala Univ, Dept Phys Chem, S-75123 Uppsala, Sweden

[3] Stockholm Univ, Dept Struct Chem, S-10691 Stockholm, Sweden

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 03期

关键词：

ruthenium modified terpyridine complex; excited state lifetime;

D O I：

10.1016/j.inoche.2003.12.007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new tridentate polypyridine ligand, 6-(2-picolyl)-2,2'-bipyridine, as well as its homoleptic Ru(II) complex has been prepared. Photophysical studies show a prolonged lifetime of the excited state compared to [Ru(tpy)2](2+), where tpy is 2,2':6',2"-terpyridine. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：337 / 340

页数：4

共 31 条

[1] Electron donor-acceptor dyads and triads based on tris(bipyridine)ruthenium(II) and benzoquinone:: Synthesis, characterization, and photoinduced electron transfer reactions [J].