Zr(IV) and Hf(IV) based metal-organic frameworks with reo-topology

被引：170

作者：

Bon, Volodymyr ^{[1
]}

Senkovskyy, Volodymyr ^{[2
]}

Senkovska, Irena ^{[1
]}

Kaskel, Stefan ^{[1
]}

机构：

[1] Tech Univ Dresden, Dept Inorgan Chem, D-01062 Dresden, Germany

[2] Leibniz Inst Polymerforsch Dresden eV, D-01069 Dresden, Germany

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 67期

关键词：

SURFACE-AREAS; ADSORPTION;

D O I：

10.1039/c2cc34246d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zr and Hf based MOFs with enhanced pore accessibility for large molecules and good hydrothermal stability were obtained using a bent dithienothiophene dicarboxylate and Zr4+ or Hf4+ source. A modulator (benzoic acid) facilitates formation of an eight-connecting cluster leading to a new framework which adopts reo topology.

引用

页码：8407 / 8409

页数：3

共 17 条

[1] Reverse shape selectivity in the adsorption of hexane and xylene isomers in MOF UiO-66 [J].

Barcia, Patrick S. ;

Guimaraes, Daniela ;

Mendes, Patricia A. P. ;

Silva, Jose A. C. ;

Guillerm, Vincent ;

Chevreau, Hubert ;

Serre, Christian ;

Rodrigues, Alirio E. .

MICROPOROUS AND MESOPOROUS MATERIALS, 2011, 139 (1-3) :67-73

[2] A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability [J].

Cavka, Jasmina Hafizovic ;

Jakobsen, Soren ;

Olsbye, Unni ;

Guillou, Nathalie ;

Lamberti, Carlo ;

Bordiga, Silvia ;

Lillerud, Karl Petter .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (42) :13850-13851

[3] Calculating geometric surface areas as a characterization tool for metal-organic frameworks [J].

Dueren, Tina ;

Millange, Franck ;

Ferey, Gerard ;

Walton, Krista S. ;

Snurr, Randall Q. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (42) :15350-15356

[4] Metal-organic frameworks as semiconductors [J].

Gomes Silva, Claudia ;

Corma, Avelino ;

Garcia, Hermenegildo .

JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (16) :3141-3156

[5] MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs) [J].

Janiak, Christoph ;

Vieth, Jana K. .

NEW JOURNAL OF CHEMISTRY, 2010, 34 (11) :2366-2388

[6] Characterization of metal-organic frameworks by water adsorption [J].

Kuesgens, Pia ;

Rose, Marcus ;

Senkovska, Irena ;

Froede, Heidrun ;

Henschel, Antje ;

Siegle, Sven ;

Kaskel, Stefan .

MICROPOROUS AND MESOPOROUS MATERIALS, 2009, 120 (03) :325-330

[7] Zirconium: Biomedical and Nephrological Applications [J].

Lee, David B. N. ;

Roberts, Martin ;

Bluchel, Christian G. ;

Odell, Ross A. .

ASAIO JOURNAL, 2010, 56 (06) :550-556

[8] Metal-Organic Frameworks for Separations [J].

Li, Jian-Rong ;

Sculley, Julian ;

Zhou, Hong-Cai .

CHEMICAL REVIEWS, 2012, 112 (02) :869-932

[9] Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal-Organic Frameworks [J].

Morris, William ;

Volosskiy, Boris ;

Demir, Selcuk ;

Gandara, Felipe ;

McGrier, Psaras L. ;

Furukawa, Hiroyasu ;

Cascio, Duilio ;

Stoddart, J. Fraser ;

Yaghi, Omar M. .

INORGANIC CHEMISTRY, 2012, 51 (12) :6443-6445

[10] The Reticular Chemistry Structure Resource (RCSR) Database of, and Symbols for, Crystal Nets [J].

O'Keeffe, Michael ;

Peskov, Maxim A. ;

Ramsden, Stuart J. ;

Yaghi, Omar M. .

ACCOUNTS OF CHEMICAL RESEARCH, 2008, 41 (12) :1782-1789

← 1 2 →