Vibrational spectra of augelites Al2(OH)3(XO3) (X = P, As, V)

被引：18

作者：

Breitinger, DK

Mohr, J

Colognesi, D

Parker, SF

Schukow, H

Schwab, RG

机构：

[1] Univ Erlangen Nurnberg, Inst Inorgan Chem, D-91058 Erlangen, Germany

[2] Rutherford Appleton Lab, Didcot OX11 0QX, Oxon, England

[3] Inst Geol & Mineral, D-91054 Erlangen, Germany

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2001年 / 563卷

关键词：

augelite; arsenatoaugelite; vanadatoaugelite; IR and Raman spectra; inelastic neutron scattering;

D O I：

10.1016/S0022-2860(00)00792-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The solid-state vibrational spectra (IR, Raman, inelastic neutron scattering (INS)) of synthetic augelites Al-2(OH)(3)(XO4) (X = P, As. V) (space group C2/m. Z = 4) are discussed on the basis of a unit-cell group analysis. The spectral effects of deuteration, especially on the deformation modes involving the two structurally different OH-groups, and of substitution in the anionic constituents in the framework are dealt with. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：377 / 382

页数：6

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