Rearrangement reactions in the electrospray ionization mass spectra of pyoverdins

被引:19
作者
Fuchs, R [1 ]
Budzikiewicz, H [1 ]
机构
[1] Univ Cologne, Inst Organ Chem, D-50939 Cologne, Germany
关键词
pyoverdins; Pseudomonas; electrospray ionization; rearrangement reaction;
D O I
10.1016/S1387-3806(01)00408-0
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
The electrospray ionization mass spectra of pyoverdins, chromopeptidic siderophores of the bacterial family Pseudomonas, especially when analyzed by collision activation in an ion trap, show rearrangement reactions which can lead to erroneous structure proposals. Several of these processes will be described. (C) 2001 Elsevier Science B.V.
引用
收藏
页码:603 / 612
页数:10
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