Non-hydrolytic sol-gel process: Zirconium titanate gels

被引:61
作者
Andrianainarivelo, M [1 ]
Corriu, RJP [1 ]
Leclercq, D [1 ]
Mutin, PH [1 ]
Vioux, A [1 ]
机构
[1] UNIV MONTPELLIER 2, LAB PRECURSEURS MOL MAT, UMR 44, F-34095 MONTPELLIER 5, FRANCE
关键词
D O I
10.1039/a605168e
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The effectiveness of a non-hydrolytic sol-gel process for the preparation of bicomponent oxides has been-studied in the 1:1 system TiO2-ZrO2. Elemental analysis by energy dispersive X-ray analysis (EDXA) and by inductively coupled plasma (ICP) showed the same Ti:Zr ratio for the amorphous oxide and crystalline ZrTiO4 which corresponds to that of the initial solution. The direct crystallization of ZrTiO4 below 700 degrees C without the intermediate formation of TiO2 or ZrO2 indicates that the non-hydrolytic sol-gel process gives rise to the formation of homogeneous zirconium titanate gels.
引用
收藏
页码:279 / 284
页数:6
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