Adducts of xenon with organic molecules: Rotational spectrum of dimethyl ether-Xe

被引：19

作者：

Favero, LB

Velino, B

Millemaggi, A

Caminati, W

机构：

[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

[2] CNR, ISMN, Sez Bologna, I-40129 Bologna, Italy

[3] Univ Bologna, Dipartimento Chim Fis & Inorgan, I-40136 Bologna, Italy

来源：

CHEMPHYSCHEM | 2003年 / 4卷 / 08期

关键词：

gas-phase reactions; noble gases; rotational spectroscopy; van der Waals adducts; xenon;

D O I：

10.1002/cphc.200300698

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A xenon adduct of an open-chain organic molecule, namely, Xe - dimethyl ether (DME), was prepared under the conditions of very low pressure and temperature that exist in the plume following a supersonic expansion. The equilibrium configuration (see picture) and dissociation energy of DME - Xe were deduced from its free-jet millimeter-wave spectrum.

引用

页码：881 / 884

页数：4

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