Synthesis and characteristics of metal-phthalocyanine-polymer composite films

被引:2
作者
Chen, JM [1 ]
Zhang, JC [1 ]
Shen, Y [1 ]
Liu, XH [1 ]
机构
[1] Shanghai Univ, Dept Inorgan Mat, Shanghai 201800, Peoples R China
来源
FOURTH INTERNATIONAL CONFERENCE ON THIN FILM PHYSICS AND APPLICATIONS | 2000年 / 4086卷
关键词
phthalocyanine; polystyrene; C-60; photoconductivity; composite films;
D O I
10.1117/12.408371
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Fe (III)-2,9,16,23-tertracarboxy-phthalocyanine (Fe (III)-taPc) was synthesized, and was bonded to polystyrene (PS) with covalence by Friedel-Crafts reaction to form a new polymer [Fe (III)-taPc-PS] [polymer (II)]. Uv-Vis and Infrared spectra indicated that Fe (III)-taPc was successfully bonded to PS. A photoreceptor device of sandwich structure consisting of alternate layers of polymer (II) and fullerene (C-60) was prepared. The experiment results show that the photoconductivity of the photoreceptor is higher than that of the single-layer film of polymer (II) or C-60 because of the charge-transfer effect between the layers.
引用
收藏
页码:749 / 752
页数:4
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