Sorption studies of 2,4-D on selected soils

被引:58
作者
Bekbölet, M [1 ]
Yenigün, O [1 ]
Yücel, I [1 ]
机构
[1] Bogazici Univ, Inst Environm Sci, TR-80815 Istanbul, Turkey
关键词
adsorption; desorption; 2,4-D; soil pollution;
D O I
10.1023/A:1005089612111
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Adsorption/desorption characteristics of the herbicide 2,4-D on various types of soils were investigated. Batch equilibrium techniques were used in the laboratory experiments. Data were fitted to the linear and Freundlich sorption equations. K and K-f values ranged between 0.32-1.89 L-1 mg and 2.6 x 10(-3) - 7.4 mg kg-(1), respectively. Results showed that both for linear and Freundlich adsorption equations, for all soils, K and K-f were correlated to the organic matter content (r = 0.87 and r = 0.66, respectively). Adsorption was also positively correlated with silt and clay content of soils (r = 0.53) and negatively correlated with sand content.
引用
收藏
页码:75 / 88
页数:14
相关论文
共 21 条
[1]  
*ASTM, 1984, D422631 ASTM, P86
[2]  
*ASTM, 1993, E119587 ASTM
[3]  
*ASTM, 1971, D221671 ASTM, P275
[4]   2,4-D DEGRADATION IN MONOCULTURE BIOFILM REACTORS [J].
CLARKSON, WW ;
YANG, CP ;
HARKER, AR .
WATER RESEARCH, 1993, 27 (08) :1275-1284
[5]  
Foth HD., 1990, FUNDAMENTALS SOIL SC
[6]   STUDIES IN ADSORPTION .11. A SYSTEM OF CLASSIFICATION OF SOLUTION ADSORPTION ISOTHERMS, AND ITS USE IN DIAGNOSIS OF ADSORPTION MECHANISMS AND IN MEASUREMENT OF SPECIFIC SURFACE AREAS OF SOLIDS [J].
GILES, CH ;
MACEWAN, TH ;
NAKHWA, SN ;
SMITH, D .
JOURNAL OF THE CHEMICAL SOCIETY, 1960, (OCT) :3973-3993
[7]  
Hamaker J.W., 1972, ORGANIC CHEM SOIL EN
[8]  
Hermosin M.C., 1992, FRESEN ENVIRON BULL, V1, P472
[9]   REMOVING 2,4-D FROM WATER BY ORGANO-CLAYS [J].
HERMOSIN, MC ;
CORNEJO, J .
CHEMOSPHERE, 1992, 24 (10) :1493-1503
[10]   ASSESSING FACTORS RELATED TO PESTICIDE ADSORPTION BY SOILS [J].
HERMOSIN, MC ;
CORNEJO, J .
TOXICOLOGICAL AND ENVIRONMENTAL CHEMISTRY, 1989, 25 (01) :45-55