First-row transition metal-halide complexes supported by a monoanionic [N2P2] ligand

被引：20

作者：

Chomitz, Wayne A. ^{[1
]}

Mickenberg, Seth F. ^{[1
]}

Arnold, John ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

INORGANIC CHEMISTRY | 2008年 / 47卷 / 01期

关键词：

D O I：

10.1021/ic701670u

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metal-halide complexes of a multidentate monoanionic ligand BuN(H)SiMe2N(CH2CH2P'Pr-2)(2), H[N2P2], with Ti, V, Cr, Mn, Fe, Co, and Ni have been isolated and characterized. X-ray crystallographic studies were performed on [N2P2]TiCl2 (3), [N2P2]CrCl2 (5), [N2P2]MnCl (6), [N2P2]FeCl (7), [N2P2]CoCl (8), and [N2P2]NiBr (9), and the results revealed that the [N2P21 ligand exhibits considerable flexibility in the manner in which it binds to first-row metals and that three distinct coordination modes are observed: k(3)-N2P (Ti), k(3) -NP2 (Mn, Fe, Co), and k(4)-N2P2 (Cr, Ni). Electrochemical (CV) data and room-temperature magnetic susceptibilities are also described.

引用

页码：373 / 380

页数：8

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