Stepwise Assembly of Coordination-Based Metal-Organic Networks

被引：56

作者：

Kaminker, Revital ^{[1
]}

Motiei, Leila ^{[1
]}

Gulino, Antonino ^{[3
]}

Fragala, Ignazio ^{[3
]}

Shimon, Linda J. W. ^{[2
]}

Evmenenko, Guennadi ^{[4
]}

Dutta, Pulak ^{[4
]}

Iron, Mark A. ^{[2
]}

van der Boom, Milko E. ^{[1
]}

机构：

[1] Weizmann Inst Sci, Dept Organ Chem, IL-76100 Rehovot, Israel

[2] Weizmann Inst Sci, Dept Chem Res Support, IL-76100 Rehovot, Israel

[3] Univ Catania, Dipartimento Sci Chim, I-95125 Catania, Italy

[4] Northwestern Univ, Dept Phys & Astron, Evanston, IL 60208 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 41期

关键词：

CONSISTENT BASIS-SETS; DENSITY FUNCTIONALS; OPTICAL-PROPERTIES; FILM FABRICATION; SURFACE; MULTILAYERS; FRAMEWORKS; ROBUST; NANOSTRUCTURES; CONSTRUCTION;

D O I：

10.1021/ja105518n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-organic networks (MONs) were created by a stepwise solution deposition approach from vinylpyridine-based building blocks and PdCl2. The combined experimental and computational study demonstrates the formation of saturated, structurally organized systems on solid supports. The rigid nature and geometry of the components are well-suited to form honeycomb and parallelogram structures, as predicted by a computational study. Detailed structural information of the new MONs was obtained by optical (UV/vis) spectroscopy, ellipsometry, atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), and synchrotron X-ray reflectivity (XRR). Notably, the XPS elemental composition indicates the formation of a palladium coordination-based network.

引用

页码：14554 / 14561

页数：8

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