Dispersion and phase separation of carbon nanotubes in ultrathin polymer films

被引:28
作者
Foster, J [1 ]
Singamaneni, S [1 ]
Kattumenu, R [1 ]
Bliznyuk, V [1 ]
机构
[1] Western Michigan Univ, Coll Engn & Appl Sci, Kalamazoo, MI 49008 USA
关键词
nanocomposite; atomic force microscopy; single-wall carbon nanotubes;
D O I
10.1016/j.jcis.2005.01.101
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The inner structure and nanoscale distribution of the stiffness Was studied for polymer-single-wall carbon nanotube composites. Dispersion of nanotubes in a polystyrene and polyurethane polymer matrix was achieved by a proper choice of the organic solvent (NMP) and sonification of polymer/SWNT solutions. Ultrathin nanocomposite films were prepared through a dip-coating procedure and possessed a noticeable degree of nanotube orientation in the direction of the applied shear force. Peculiarities of the phase separation in the films were studied by atomic force microscopy (with application of force modulation mode to map the nanotube distribution within the polymer matrix) and Raman spectroscopy. (c) 2005 Elsevier Inc. All rights reserved.
引用
收藏
页码:167 / 172
页数:6
相关论文
共 32 条
[1]   Stabilization of individual carbon nanotubes in aqueous solutions [J].
Bandyopadhyaya, R ;
Nativ-Roth, E ;
Regev, O ;
Yerushalmi-Rozen, R .
NANO LETTERS, 2002, 2 (01) :25-28
[2]   Carbon nanotube actuators [J].
Baughman, RH ;
Cui, CX ;
Zakhidov, AA ;
Iqbal, Z ;
Barisci, JN ;
Spinks, GM ;
Wallace, GG ;
Mazzoldi, A ;
De Rossi, D ;
Rinzler, AG ;
Jaschinski, O ;
Roth, S ;
Kertesz, M .
SCIENCE, 1999, 284 (5418) :1340-1344
[3]   Noncovalent sidewall functionalization of single-walled carbon nanotubes for protein immobilization [J].
Chen, RJ ;
Zhang, YG ;
Wang, DW ;
Dai, HJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (16) :3838-3839
[4]   Continuous convective assembling of fine particles into two-dimensional arrays on solid surfaces [J].
Dimitrov, AS ;
Nagayama, K .
LANGMUIR, 1996, 12 (05) :1303-1311
[5]   Processing and characterization of carbon nanotube/poly(styrene-co-butyl acrylate) nanocomposites [J].
Dufresne, A ;
Paillet, M ;
Putaux, JL ;
Canet, R ;
Carmona, F ;
Delhaes, P ;
Cui, S .
JOURNAL OF MATERIALS SCIENCE, 2002, 37 (18) :3915-3923
[6]  
Dujardin E, 1998, ADV MATER, V10, P1472, DOI 10.1002/(SICI)1521-4095(199812)10:17<1472::AID-ADMA1472>3.0.CO
[7]  
2-R
[8]   Block copolymer thin films: pattern formation and phase behavior [J].
Green, PF ;
Limary, R .
ADVANCES IN COLLOID AND INTERFACE SCIENCE, 2001, 94 (1-3) :53-81
[9]   Wetting and dynamics of structured liquid films [J].
Green, PF .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2003, 41 (19) :2219-2235
[10]   Functionalization of single-walled carbon nanotubes with (R-)oxycarbonyl nitrenes [J].
Holzinger, M ;
Abraha, J ;
Whelan, P ;
Graupner, R ;
Ley, L ;
Hennrich, F ;
Kappes, M ;
Hirsch, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (28) :8566-8580