A cyanide-bridged bimetallic complex, [CrPr(CN)6(C3H7NO)4(H2O)3]•H2O

被引：12

作者：

Combs, RA ^{[1
]}

Farmer, JM ^{[1
]}

Kautz, JA ^{[1
]}

机构：

[1] Baylor Univ, Dept Chem & Biochem, Waco, TX 76798 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2000年 / 56卷 / 12期

关键词：

D O I：

10.1107/S010827010001204X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of the bimetallic cyanide-bridged title complex, triaqua-1 kappa (3) O-mu -cyano-1:2 kappa (2) N:C-pentacyano-2 kappa (5) C-tetrakis(N,N-dimethylformamide)-1 kappa O-4-chromium(III)praseodymium(III) monohydrate, was obtained by single-crystal Xray diffraction. The central praseodymium(III) ion is eight-coordinate, arranged in a square antiprism, while the chromium(III) ion is six-coordinate, oriented octahedrally. Molecules in the crystal lattice are held together by a network of hydrogen bonds.

引用

页码：1420 / 1422

页数：3

共 12 条

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