CuBi7I19(C4H8O3H)3(C4H8O3H2), a novel complex bismuth iodide containing one-dimensional [CuBi5I19]3- chains

被引：54

作者：

Feldmann, C ^{[1
]}

机构：

[1] Philips Res Labs, D-52066 Aachen, Germany

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 04期

关键词：

D O I：

10.1021/ic000713i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation and crystal structure of the novel complex bismuth iodide CuBi7I19 (C4H8O3H)3 (C4H8O3H2) is reported. By reaction of CuI and BiI3 in diethylene glycol, the compound is prepared at comparably low temperatures (140°C). The crystal structure can be subdivided into one-dimensional anionic [CuBi5I19]3- chains along [101] and [Bi2 (C4H8O3H2)3 (C4H8O3H2)]3+ cations.

引用

页码：818 / 819

页数：2

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