Highly active metallocene catalysts for olefin polymerization

被引：504

作者：

Kaminsky, W ^{[1
]}

机构：

[1] Univ Hamburg, Inst Tech & Macromol Chem, D-20146 Hamburg, Germany

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 09期

关键词：

D O I：

10.1039/a800056e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The fascinating story of the discovery of the metallocene-methylaluminoxane catalysts for olefin polymerization is reviewed from its conception up until the first commercial production of polymers. A great number of different titanocenes and zirconocenes have been synthesized that give tailored polymers of totally different structures, and allows control of polymer tacticity, molecular weight and molecular weight distribution to be more efficient. New kinds of copolymers and elastomers can be synthesized.

引用

页码：1413 / 1418

页数：6

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