Nonvolatile Me3P-like P-donor ligand:: Synthesis and properties of 4-phenyl-1-phospha-4-silabicyclo[2.2.2]octane

被引：43

作者：

Ochida, A ^{[1
]}

Hara, K ^{[1
]}

Ito, H ^{[1
]}

Sawamura, M ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Sci, Div Chem, Sapporo, Hokkaido 0600810, Japan

来源：

ORGANIC LETTERS | 2003年 / 5卷 / 15期

关键词：

D O I：

10.1021/ol0349099

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] A new trialkylphosphine ligand with Me3P-like steric and electronic properties, 4-phenyl-1-phospha-4-silabicyclo[2.2.2]octane (Ph-SMAP), was synthesized. Given a phenyl group at the silicon atom, the Ph-SMAP ligand displayed nonvolatility with retention of Me3P-like properties. The new ligand was air-stable, crystalline, and easy to handle.

引用

页码：2671 / 2674

页数：4

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