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The potential of palladacycles: More than just precatalysts

被引：1237
作者：
Dupont, J
Consorti, CS
Spencer, J
机构：
[1] Univ Fed Rio Grande do Sul, Inst Chem, Lab Mol Catalysis, BR-91501970 Porto Alegre, RS, Brazil
[2] James Black Fdn, London SE24 9JE, England
来源：
CHEMICAL REVIEWS | 2005年 / 105卷 / 06期
关键词：
D O I：
10.1021/cr030681r
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This review covers isolated and well-defined compounds that contain a Pd-C bond stabilized by the intramolecular coordination of one or two neutral donor atoms (N, P, As, O, Se, or Se). Topics discussed include the methods of preparation, chiral cyclopalladated compounds, palladacycles in medicinal and biological chemistry, functionalization of Pd-C bonds, palladacycles as catalyst precursors, total syntheses, caveats, photoluminescent palladacycles, liquid crystals, and supramolecules and dendrimers.
引用
收藏
页码：2527 / 2571
页数：45
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