Metal-organic nanoporous structures with anisotropic photoluminescence and magnetic properties and their use as sensors

被引:387
作者
Harbuzaru, Bogdan V. [1 ]
Corma, Avelino [1 ]
Rey, Fernando [1 ]
Atienzar, Pedro [1 ]
Jorda, Jose L. [1 ]
Garcia, Hermenegildo [1 ]
Ananias, Duarte [2 ]
Carlos, Luis D. [2 ]
Rocha, Joao [2 ]
机构
[1] Univ Politecn Valencia, Inst Tecnol Quim, E-46022 Valencia, Spain
[2] Univ Aveiro, Dept Chem & Phys, CICECO, P-3810193 Aveiro, Portugal
关键词
lanthanides; luminescence; metal-organic frameworks; microporous materials; sensors;
D O I
10.1002/anie.200704702
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Shining bright: Porous metal-organic framework materials are important owing to their potential applications as sensors. A new family of nanoporous, multifunctional rare-earth metal-organic materials displays emission quantum yields and efficiencies that are the highest reported for solid-state Eu3+ compounds with organic ligands and magnetic properties. The picture shows [Gd,Eu]- and [Tb]-containing materials under UV light and interacting with a magnet. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:1080 / 1083
页数:4
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