A new approach to 4-alkylthio-1,3-dithiole-2-thione: An unusual reaction of a zinc complex of 1,3-dithole-2-thione-4,5-dithiolate

被引：44

作者：

Jia, CY ^{[1
]}

Zhang, DQ ^{[1
]}

Xu, W ^{[1
]}

Zhu, DB ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Organ Solids Lab, Beijing 100080, Peoples R China

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 12期

关键词：

D O I：

10.1021/ol015990n

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] A new and facile approach to 4-alkylthio-1,3-dithiole-2-thione starting from easily accessible reactants was described, This approach was based on the unusual reaction of a zinc complex of 1,3-dithiole-2-thione-4,5-dithiolate with electrophilic reagents in the presence of 3-picolyl chloride hydrochloride/or 4-picolyl chloride hydrochloride/or pyridine hydrochloride.

引用

页码：1941 / 1944

页数：4

共 12 条

[1] SYNTHESIS OF 1,3-DISELENOLE-2-SELONES AND 1,3-DISELENOLE-2-THIONES [J].

BECHGAARD, K ;

COWAN, DO ;

BLOCH, AN ;

HENRIKSEN, L .

JOURNAL OF ORGANIC CHEMISTRY, 1975, 40 (06) :746-749

[2] Studies on the electroactive heterocycles C6S80/2- and C6S6O20/2- and related metal complexes [J].

Chou, JH ;

Rauchfuss, TB ;

Szczepura, LF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (08) :1805-1811

[3] ORGANIC ALLOYS - SYNTHESIS AND PROPERTIES OF SOLID-SOLUTIONS OF TETRASELENAFULVALENE-TETRACYANO-PARA-QUINODIMETHANE (TSEF-TCNQ) AND TETRATHIAFULVALENE-TETRACYANO-PARA-QUINODIMETHANE (TTF-TCNQ) [J].

ENGLER, EM ;

SCOTT, BA ;

ETEMAD, S ;

PENNEY, T ;

PATEL, VV .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (18) :5909-5916

[4] ELECTROCHEMICAL SYNTHESIS OF TETRATHIOETHYLENES [J].

FALSIG, M ;

LUND, H .

ACTA CHEMICA SCANDINAVICA SERIES B-ORGANIC CHEMISTRY AND BIOCHEMISTRY, 1980, 34 (08) :591-595

[5] ELECTRON-TRANSFER IN A NEW HIGHLY CONDUCTING DONOR-ACCEPTOR COMPLEX [J].

FERRARIS, J ;

WALATKA, V ;

PERLSTEI.JH ;

COWAN, DO .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (03) :948-949

[6] BINARY CARBON SULFIDES BASED ON THE ALPHA-C3S5 SUBUNIT AND RELATED C-S-O, C-S-CL, AND C-S-N COMPOUNDS [J].

GALLOWAY, CP ;

DOXSEE, DD ;

FENSKE, D ;

RAUCHFUSS, TB ;

WILSON, SR ;

YANG, XG .

INORGANIC CHEMISTRY, 1994, 33 (20) :4537-4544

[7] Tetraalkyl- and dialkyl-substituted BEDT-TTF derivatives and their cation-radical salts: synthesis, structure, and properties [J].

Kini, AM ;

Parakka, JP ;

Geiser, U ;

Wang, HH ;

Rivas, F ;

DiNino, E ;

Thomas, S ;

Dudek, JD ;

Williams, JM .

JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (04) :883-892

[8] Syntheses of new electron donors with hydroxymethyl groups and studies on their cation-radical salts [J].

Li, HX ;

Zhang, DQ ;

Zhang, B ;

Yao, YX ;

Xu, W ;

Zhu, DB ;

Wang, ZM .

JOURNAL OF MATERIALS CHEMISTRY, 2000, 10 (09) :2063-2067

[9]

MORIKAMI TA, 1997, SYNLETT, P319

[10]

SVENSTRUP N, 1995, SYNTHESIS-STUTTGART, P215

← 1 2 →