Copper-catalyzed arylation of amines using diphenyl pyrrolidine-2-phosphonate as the new ligand

被引：126

作者：

Rao, HH

Fu, H ^{[1
]}

Jiang, YY

Zhao, YF

机构：

[1] Tsinghua Univ, Dept Chem, Minist Educ, Key Lab Bioorgan Phosphorous Chem & Chem Biol, Beijing 100084, Peoples R China

[2] Tsing Hua Univ, Grad Sch Shenzhen, Key Lab Chem Biol, Shenzhen 518057, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2005年 / 70卷 / 20期

关键词：

D O I：

10.1021/jo051221w

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We have developed a general, efficient, and inexpensive catalyst system for arylation of amines by using 10 mol % of CuI as the copper source, 20 mol % of diphenyl pyrrolidine-2-phosphonate (DPP) as the ligand, K3PO4 as the base, and DMF containing 2% water (v/v) as the solvent.

引用

页码：8107 / 8109

页数：3

共 33 条

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