Bis(N-cyclohexyl-N-ethyldithiocarbamato-S,S′)lead(II)

被引：3

作者：

Baba, I

Farina, Y

Othman, AH

Razak, IA

Fun, HK

Ng, SW ^{[1
]}

机构：

[1] Univ Malaya, Inst Postgrad Studies, Kuala Lumpur 50603, Malaysia

[2] Univ Kebangsaan Malaysia, Sch Chem Sci, Bangui 43600, Selangor, Malaysia

[3] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, George Town 11800, Malaysia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2001年 / 57卷

关键词：

D O I：

10.1107/S1600536800020146

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The Pb atom in the title compound, [Pb(C9H16NS2)(2)], is chelated in an anisobidentate manner by the dithiocarbamate group [Pb-S = 2.710 (2)/2.883(2) Angstrom and 2.700 (2)/2.841(2) Angstrom]. The four-coordinate geometry is raised to six through the involvement of the double-bonded S atoms of adjacent dithiocarbamato groups; the Pb . . .S interactions [Pb . . .S = 3.457 (2) and 3.508 (2) Angstrom] result in a chain structure for the compound.

引用

页码：M35 / M36

页数：2

共 9 条

[1] STRUCTURE OF LEAD(II) N,N-DIISOPROPYLDITHIOCARBAMATE [BIS(N,N-DIISOPROPYLDITHIOCARBAMATO)LEAD(II)] [J].

ITO, M ;

IWASAKI, H .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1980, 36 (FEB) :443-444

[2] STRUCTURE OF BIS(N,N-DIMETHYLDITHIOCARBAMATO)LEAD(II) [J].

IWASAKI, H .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1980, 36 (SEP) :2138-2139

[3]

Johnson C. K., 1976, ORNL5138

[4]

NG SW, 1999, ACTA CRYST C, V55

[5]

Sheldrick G. M., 1997, SHELXS 97 PROGRAM CR

[6]

Sheldrick G.M., 1996, SADABS VERSION 2008

[7]

Siemens, 1996, SAINT SMART

[8] Synthesis of PbS nanocrystallites using a novel single molecule precursors approach: X-ray single-crystal structure of Pb(S2CNEtPri)2 [J].

Trindade, T ;

OBrien, P ;

Zhang, XM ;

Motevalli, M .

JOURNAL OF MATERIALS CHEMISTRY, 1997, 7 (06) :1011-1016

[9]

ZVONKOVA ZN, 1967, SOV PHYS-CRYSTALLOGR, V12, P926

← 1 →