Polymers with pendent functional groups VII. Polysaccharide derivatives containing viologen groups

被引:10
作者
Avram, E
Lacatus, C
Mocanu, G
机构
[1] Petru Poni Inst Macromol Chem, R-6600 Iasi, Romania
[2] Gr T Popa Univ Med & Pharm, Iasi 6600, Romania
关键词
polysaccharides; dipyridyl; viologen compounds; dextran derivatives;
D O I
10.1016/S0014-3057(01)00030-1
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The paper presents the synthesis of new polysaccharide derivatives containing viologen groups, by reaction of chloroacetylated crosslinked dextran microparticles with dipyridyl compounds as: 4,4 ' dipyridyl. N-n-octyidipyridinium chloride and N-benzyldipyridinium chloride. The influence of the reaction conditions on the substitution degree with dipyridyl groups was discussed and a reaction mechanism was proposed. Some preliminary studies concerning antimicrobial activity of the polymeric dipyridyl compounds were also reported. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1901 / 1906
页数:6
相关论文
共 21 条
[1]  
BALS M, 1982, LAB CLIN INFECT, V2
[2]  
BILBIE V, 1999, TRATAT MICROBIOLOGIE
[3]  
BILBIE V, 1985, BACTERIOLOGIE MED, V2
[4]  
BILBIE V, 1992, MICROBIOLOGIE MED
[5]   Polymers with pendent functional groups IV.: The reaction of chloromethylated polystyrene with N-phenacyl-4,4′-bipyridinium bromides [J].
Druta, I ;
Avram, E ;
Cozan, V .
EUROPEAN POLYMER JOURNAL, 2000, 36 (01) :221-224
[6]   REDUCTION OF METHYL BENZOYLFORMATE BY DIHYDRONICOTINAMIDE IN THE PRESENCE OF POLYMERIC VIOLOGENS AS ELECTRON MEDIATOR [J].
ENDO, T ;
TAKADA, T ;
KAMEYAMA, A ;
OKAWARA, M .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1991, 29 (01) :135-137
[7]   POLYVIOLOGENS - NOVEL CLASS OF CATIONIC POLYELECTROLYTE REDOX POLYMERS [J].
FACTOR, A ;
HEINSOHN, GE .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER LETTERS, 1971, 9 (04) :289-&
[8]  
IANCU LS, 1996, MED MICROBIOLOGY, V144, P154
[9]  
JINGJI J, 1999, MAKROMOL RAPID COMMU, V20, P135
[10]   ELECTRON RELAY IN POLYMER SYSTEMS - EFFECTIVE ELECTRON-TRANSFER FROM DIHYDRONICOTINAMIDE TO VIOLOGEN MOIETIES IN THEIR COPOLYMERS [J].
KAMEYAMA, A ;
NAMBU, Y ;
ENDO, T .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1992, 30 (06) :1199-1202