Infrared spectra and structure of hydrogen bonds in N′-substituted isonicotinic hydrazides formed by crystallization from solution and via solid phase transformations

被引：8

作者：

Atovmyan, YG ^{[1
]}

Nikonova, LA ^{[1
]}

Chuev, II ^{[1
]}

Utenyshev, AN ^{[1
]}

Aldoshina, MZ ^{[1
]}

Aldoshin, SM ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Chem Phys Chernogolovka, Moscow 142432, Russia

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1999年 / 474卷

关键词：

N '-substituted isonicotinic hydrazides; intermolecular hydrogen bond; IR spectroscopy; crystallization;

D O I：

10.1016/S0022-2860(98)00570-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Crystal chemical and IR spectroscopic data for N'-substituted isonicotinic hydrazides (INH) of the general formula Py-C(=O)-N(H)-N'=C(H)-R [R = thineyl, furyl, 5-nitrofuryl, and o-nitrophenyl] have been analysed. Crystalline compounds (hydrates, solvates, solvate hydrates, salts) of a specified composition and structure, i.e. a desired system of intermolecular hydrogen bonds, can be obtained by deliberately varying the solvent composition during synthesis or recrystallization. The systematic effects of substituent R on composition and structure of INH solvates and on their thermodynamic stability have been revealed. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：167 / 175

页数：9

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