Observation of a high lying van der Waals mode in the intermolecular potential of Ar-CO

被引：16

作者：

Scheele, I ^{[1
]}

Lehnig, R ^{[1
]}

Havenith, M ^{[1
]}

机构：

[1] Ruhr Univ Bochum, Lehrstuhl Physikal Chem II, D-44780 Bochum, Germany

来源：

MOLECULAR PHYSICS | 2001年 / 99卷 / 03期

关键词：

D O I：

10.1080/00268970010008351

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A continuous two-dimensional jet expansion in combination with an infrared diode laser spectrometer has been used to record a new subband of the weakly bound complex Ar-CO in the 2168 cm(-1) region. Twenty-two transitions were assigned to a thus far unobserved K-a = 0 van der Waals state at 36.765 cm(-1) above the ground state. This is the highest van der Waals mode of Ar-CO reported so far. These high lying energy levels will provide a very sensitive test for future ab initio and semiempirical potential energy surfaces.

引用

页码：205 / 209

页数：5

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