Plasma-assisted process for removing NO/NOx from gas streams with C2H4 as additive

被引:11
作者
Lee, HM [1 ]
Chang, MB [1 ]
Yang, SC [1 ]
机构
[1] Natl Cent Univ, Grad Inst Environm Engn, Chungli 320, Taiwan
来源
JOURNAL OF ENVIRONMENTAL ENGINEERING-ASCE | 2003年 / 129卷 / 09期
关键词
vapor; abatement and removal; air pollution; contaminants;
D O I
10.1061/(ASCE)0733-9372(2003)129:9(800)
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
NOx removal from gas streams via dielectric barrier discharges (DBDs) has been experimentally evaluated. This paper investigates the effect of injecting C2H4 as an additive with respect to the De-NOx chemistry and the effect of gas composition on NO/NOx removal efficiencies. Experimental results indicate that both removal efficiencies of NO and NOx are enhanced with increasing applied voltage, gas temperature, and water vapor. Water vapor in gas streams has a distinct influence on NOx, removal by generating OR radicals to convert NO2 to form HNO3. NOx removal decreases with increasing oxygen content although NO removal increases with increasing oxygen content. As high as 100% of NO and 57% of NOx are removed at 140degreesC for the gas stream containing [NO]:[C2H4]:[H2O(g)]:[O-2]:[N-2]=0.05:0.2:3.0:5.0:91.75. Major mechanisins. for NO and NOx removals in DBD processing with C2H4 as an additive are described in the text.
引用
收藏
页码:800 / 810
页数:11
相关论文
共 59 条
[1]  
Albritton D.L., 1978, ATOM DATA NUCL DATA, V22, P1, DOI DOI 10.1016/0092-640X(78)90027-X
[2]   Evaluated kinetic and photochemical data for atmospheric chemistry: Supplement VI - IUPAC subcommittee on gas kinetic data evaluation for atmospheric chemistry [J].
Atkinson, R ;
Baulch, DL ;
Cox, RA ;
Hampson, RF ;
Kerr, JA ;
Rossi, MJ ;
Troe, J .
JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1997, 26 (06) :1329-1499
[3]  
ATKINSON R, 1992, J PHYS CHEM REF DATA, V21, P6
[4]   EVALUATED KINETIC DATA FOR COMBUSTION MODELING SUPPLEMENT-I [J].
BAULCH, DL ;
COBOS, CJ ;
COX, RA ;
FRANK, P ;
HAYMAN, G ;
JUST, T ;
KERR, JA ;
MURRELLS, T ;
PILLING, MJ ;
TROE, J ;
WALKER, RW ;
WARNATZ, J .
JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1994, 23 (06) :847-1033
[5]   Formation of HO2 from OH and C2H2 in the presence of O2 [J].
Bohn, B ;
Zetzsch, C .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1998, 94 (09) :1203-1210
[6]   Kinetics of the N+NCO reaction at 298 K [J].
Brownsword, RA ;
Hancock, G ;
Heard, DE .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1997, 93 (15) :2473-2475
[7]  
CHANG M B, 1992, Environmental Science and Technology, V26, P777, DOI 10.1021/es00028a017
[8]   Plasma-assisted removal of NO from gas streams via ammonia injection [J].
Chang, MB ;
Cheng, CF .
ENVIRONMENTAL ENGINEERING SCIENCE, 1997, 14 (04) :193-200
[9]   Low temperature SNCR process for NOx control [J].
Chang, MB ;
Cheng, CF .
SCIENCE OF THE TOTAL ENVIRONMENT, 1997, 198 (01) :73-78
[10]   PRODUCT CHANNEL DYNAMICS OF THE NCO+NO REACTION [J].
COOPER, WF ;
PARK, J ;
HERSHBERGER, JF .
JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (13) :3283-3290