Controlled assembly and solution observation of a 2.6 nm polyoxometalate 'super' tetrahedron cluster:: [KFe12(OH)18(α-1,2,3-P2W15O56)4]29-

被引：111

作者：

Pradeep, Chullikkattil P.

Long, De-Liang

Koegerler, Paul

Cronin, Leroy

机构：

[1] Univ Glasgow, Dept Chem, WestCHEM, Glasgow G12 8QQ, Lanark, Scotland

[2] Iowa State Univ, Ames Lab, Ames, IA 50011 USA

[3] Iowa State Univ, Dept Phys, Ames, IA 50011 USA

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 41期

关键词：

D O I：

10.1039/b707202c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A nanoscale Fe-III-substituted polyoxotungstate [KFe12(OH) (-)(18) (alpha-1,2,3-P2W15O56)(4)](29-) is synthesized starting from the trilacunary {P2W15} Dawson cluster and [Fe-3(mu(3)-O)( CH2 =CHCOO)(6)(H2O)(3)](1+) to give a 2.6 nm tetrahedral cluster species and the 16 kDa cluster can be directly observed in solution as revealed by mass spectrometry studies.

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页码：4254 / 4256

页数：3

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