Poly[diaquahexakis(dimethyl sulfoxide-κO)cerium [(μ2-hexacosaoxooctamolybdate)sodium]]

被引：8

作者：

Chen, LJ ^{[1
]}

Lu, CZ ^{[1
]}

Zhang, QZ ^{[1
]}

Chen, SM ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2005年 / 61卷

关键词：

D O I：

10.1107/S0108270105010206

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, {[Ce(C2H6OS)(6)(H2O)(2)][NaMo8O26]}(n), contains an infinite chain of beta-octamolybdate moieties linked by Na+ ions, and further linked into a two-dimensional network by [Ce(DMSO)(6)(H2O)(2)](3+) (DMSO is dimethyl sulfoxide) groups via hydrogen-bond interactions. The Ce and Na atoms are located on a twofold axis and an inversion centre, respectively.

引用

收藏

页码：M269 / M271

页数：3

相关论文

共 15 条

[1] BOND-VALENCE PARAMETERS FOR SOLIDS [J].

BRESE, NE ;

OKEEFFE, M .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1991, 47 :192-197

[2] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE [J].

BROWN, ID ;

ALTERMATT, D .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG) :244-247

[3]

CHEM SM, 2004, ACTA CRYSTALLOGR C, V60, pM549

[4] A new polyoxomolybdate infinite chain complex containing β-[Mo8O26]4- linked up by two bonded Ag+ ions:: {(Bu4N)2Ag2[Mo8O26]}n [J].

Chen, SM ;

Lu, CZ ;

Yu, YQ ;

Zhang, QZ ;

He, X .

INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (09) :1041-1044

[5] Polyoxomolybdate clusters and tetranuclear copper-organonitrogen complexes as building blocks for the design of three-dimensional oxide frameworks [J].

Hagrman, D ;

Zubieta, J .

COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE, 2000, 3 (03) :231-240

[6] Composite solids constructed from one-dimensional coordination polymer matrices and molybdenum oxide subunits: Polyoxomolybdate clusters within [{Cu(4,4'-bpy)}(4)Mo8O26] and [{Ni(H2O)(2)(4,4'-bpy)(2)}(2)Mo8O26] and one-dimensional oxide chains in [{Cu(4,4'-bpy)}(4)Mo15O47]center dot 8H(2)O [J].

Hagrman, D ;

Zubieta, C ;

Rose, DJ ;

Zubieta, J ;

Haushalter, RC .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (08) :873-876

[7] Solid state coordination chemistry: two-dimensional oxides constructed from polyoxomolybdate clusters and copper-organoamine subunits [J].

Hagrman, D ;

Sangregorio, C ;

O'Connor, CJ ;

Zubieta, J .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (22) :3707-3709

[8] A novel 1D ladder-like organic-inorganic hybrid compound [(Cu(bIz)2)]2[{Cu(bIz)2}2Mo8O26] (bIz = benzimidazole) [J].

Luo, JH ;

Hong, MC ;

Wang, RH ;

Shi, Q ;

Cao, R ;

Weng, JB ;

Sun, RQ ;

Zhang, HH .

INORGANIC CHEMISTRY COMMUNICATIONS, 2003, 6 (06) :702-705

[9]

Pope M.T., 1983, HETEROPOLY ISOPOLY O

[10] POLYOXOMETALATE CHEMISTRY - AN OLD FIELD WITH NEW DIMENSIONS IN SEVERAL DISCIPLINES [J].

POPE, MT ;

MULLER, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (01) :34-48