Preparation and structural characterization of stable Cs2O closed-cage structures

被引：17

作者：

Albu-Yaron, A

Arad, T

Popovitz-Biro, R

Bar-Sadan, M

Prior, Y

Jansen, M

Tenne, R ^{[1
]}

机构：

[1] Weizmann Inst Sci, Dept Mat & Interfaces, IL-76100 Rehovot, Israel

[2] Weizmann Inst Sci, Electron Microscopy Unit, IL-76100 Rehovot, Israel

[3] Weizmann Inst Sci, Dept Chem Phys, IL-76100 Rehovot, Israel

[4] Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 27期

关键词：

cage compounds; cesium; electron microscopy; nanostructures; oxides;

D O I：

10.1002/anie.200500356

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Fullerene-like Cs2O nanoparticles were prepared by laser ablation of 3R-Cs2O powder in evacuated quartz ampoules. The Cs2O closed cages, such as the faceted nanoparticle shown in the picture, are remarkably stable as compared with the corresponding extremely unstable but technically important bulk compound, which makes them potentially useful in applications involving cesium oxide coatings, for example, photoemissive devices and catalytic converters. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4169 / 4172

页数：4

共 20 条

[1] Characterization of oxides of cesium [J].